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排序方式: 共有451条查询结果,搜索用时 15 毫秒
1.
根据碳氢燃料化学反应系统具有层次结构的特性,本文通过分析二甲醚(DME)与液化石油气(LPG)的详细化学反应机理,构建了反映DME/LPG混合燃料均质压燃(HCCI)燃烧的详细化学反应机理.采用该机理应用单区燃烧模型对DME/LPG混合燃料HCCI燃烧的化学反应动力学过程进行了数值计算.计算结果与试验结果对比表明,所构建的DME/LPG混合燃料氧化的详细化学反应机理能够准确预测DME/LPG混合燃料的两阶段放热特性,对低温和高温着火始点的预测很好;但高温反应过程预测欠佳,高温反应机理需要改进. 相似文献
2.
V. P. Bubnov I. S. Krainskii E. E. Laukhina E. B. Yagubskii 《Russian Chemical Bulletin》1994,43(5):746-750
The effect of the parameters of the electric arc (helium pressure, current and voltage, clearance between electrodes) and of the peculiarities of the setup design (arrangement of electrodes, distance between the arc and the cooling surface, temperature of the soot condensation surface) on the yield of fullerenes has been studied. Conditions for producing soot with a C60 and C70 content up to 43% (toluene extract) have been found.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 805–809, May, 1994.The authors are grateful to N. G. Spitsyna and A. V. Dubovitskii for the determination of the content of C60 and C70 fullerenes in the extract.The work was financially supported by the Russian Foundation for Basic Research (Project 93-03-18705). 相似文献
3.
A method has been developed to determine the boiling point distribution of sulfur compounds in light cycle oils (LCO'S). The method chosen for this analysis was GC with a flame photometric detector (FPD) and pyrolyzer. Tests were carried out to evaluate the recovery efficiency, repeatability, and accuracy of the method. Repeatabilities within 2% were obtained. The recovery of benzothiophenes and dibenzothiophenes was close to 100%; this was important because these are the major sulfur components in LCO's. No hydrocarbon or solvent interferences were observed with the use of the pyrolyzer, even for a 95% solvent level. Comparison with results from other techniques showed that the method accurately determined the levels of sulfur compounds in the LCO boiling point range. 相似文献
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超微粒La-Co氧化物催化剂对柴油机尾气碳黑催化燃烧性能的研究 总被引:4,自引:1,他引:4
用有机酸络合法制备了Co3O4,NiCo2O4和LaCo2O43种催化剂。通过程序升温氧化反应(TPO)技术对这3种催化剂进行模拟柴油碳黑催化燃烧反应的活性评价。研究发现以Co3O4为活性成分的催化剂能显著降低碳黑燃烧的温度。以Ni和La部分取代Co3O4后形成的复合氧化物NiCo2O4和混合氧化物LaCo2O4能改进Co3O4的氧化活性。但是NiCo2O4不能改进碳黑在松散接触时的燃烧活性;而混合氧化物LaCo2O4由于形成了超微粒含缺陷的LaCoO3钙钛矿型结构,它具有良好的低温氧化活性和表面原子移动性,因而能显著改进碳黑在松散接触时的燃烧活性。 相似文献
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The gas phase reaction between CO2 and lanthanide atoms. A test of a model for the isokinetic effect
Summary Co3O4, NiCo2O4 and LaCo2O4catalysts were synthesizedby the citric acid-ligated method. These catalysts containing Co-oxide active components can largely
lower the temperature of soot combustion under tight contact conditions. Under the conditions of loose contact NiCo2O4 cannot promote soot combustion, but LaCo2O4 can effectively promote soot combustion because the nanometric perovskite-type catalyst LaCoO3produced in the LaCo2O4sample.</o:p> 相似文献
8.
气相色谱-原子发射光谱联用技术测定柴油中硫化物 总被引:13,自引:8,他引:13
采用气相色谱-原子发射光谱(GC-AED)联用技术对柴油中硫化物进行了定性定量研究,考察了柴油加氢脱硫处理前后硫化物的变化及不同柴油原料硫化物的分布情况。结果表明,1#柴油可定性出33类硫化物,经加氢脱硫处理后,1-1#和1-2#样品硫含量可由1497mg/L分别降到165.1mg/L和90.4mg/L,平均脱除率为89.0%和94.0%。其中噻吩或苯并噻吩的脱除率为100%;C1二苯并噻吩的肿除率为90.0%和96.2%;C2二苯并噻吩的脱除率为80.6%和91.7%;C3二苯并噻吩的脱除率为72.6%和84.4%;C4二苯并噻吩的脱除率为79.0%和90.3%;C5或C6二苯并噻吩的脱除率为58.4%和68.4%;未知硫化物脱除率95.7%和97.9%。噻吩类脱除率视取代基的大小、个数和取代位置的不同脱除率不同;不同原料 总硫和各种硫化物含量差别很大,应根据其硫化物的分布特点,有针对性地研制开发加氢脱硫的催化剂及选择合适的加工工艺。 相似文献
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10.
Alfredo Carrascull Claudia Grzona Daniela Lick Marta Ponzi Esther Ponzi 《Reaction Kinetics and Catalysis Letters》2002,75(1):63-68
The catalytic combustion of particulate material was studied on cobalt catalysts promoted with potassium using different supports for its preparation. Silica, aluminium oxides and hydroxides, zirconium oxide and hydroxide were used as supports. The catalytic activity for combustion depends on the type of support used, the higher activity corresponding to the supported catalyst on zirconium oxide. TPR studies indicate that the interaction metal/support allows to explain the higher activity of the CoK/SiO2 catalyst with respect to the CoK/Al2O3 but the high activity found in CoK/ZrO2is not explained by this interaction. In all cases the Co and K improved the performance of the catalysts. 相似文献